Synthesis of Corrosion Inhibitor Based on Polymethyl Methacrylate and Investigation of Inhibition Efficiency on Carbon Steel in a 1 M HCl Medium

Synthesis of Corrosion Inhibitor Based on Polymethyl Methacrylate and Investigation of Inhibition Efficiency on Carbon Steel in a 1 M HCl Medium

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© 2024 by IJETT Journal
Volume-72 Issue-3
Year of Publication : 2024
Author : Choriev I.K, Turaev Kh. Kh, Normurodov B.A, Muzaffarova N. Sh, Мukumova G.J, Kholboeva A. I
DOI : 10.14445/22315381/IJETT-V72I3P120

How to Cite?

Choriev I.K, Turaev Kh. Kh, Normurodov B.A, Muzaffarova N. Sh, Мukumova G.J, Kholboeva A. I, "Synthesis of Corrosion Inhibitor Based on Polymethyl Methacrylate and Investigation of Inhibition Efficiency on Carbon Steel in a 1 M HCl Medium," International Journal of Engineering Trends and Technology, vol. 72, no. 3, pp. 218-229, 2024. Crossref, https://doi.org/10.14445/22315381/IJETT-V72I3P120

Abstract
The newly composite corrosion inhibitors have been synthesized from monoethanolamine, methyl methacrylate, and phosphoric acid, and their inhibition efficiency was studied. In this case, the mole ratio of the initial substances was maintained at 1:2:2, respectively, and the temperature remained between 35 0C and 40 0C, and 48 hrs. time duration was also been followed. The composition of this obtained composite corrosion inhibitor was studied by spectroscopic techniques and also quantum chemical calculation. In addition, the decomposition rate was determined using DTA and TGA processes. Moreover, the inhibition efficiency of this corrosion inhibitor (MMF-1) was studied using electrochemical measurements at different temperatures and concentrations. Polarization measurements have been carried out, and analysis of anodic and cathode slopes of polarization curves has shown that this inhibitor is a mixed-type inhibitor. Furthermore, the formation of protective films on carbon steel surfaces was confirmed by analyzing scanning electron microscopy and atomic force microscopy. Specially inhibition mechanism of this corrosion inhibitor was widely studied at temperatures of 298, 303, 313, and 323 K and unequivocally confirmed that it follows the Langmuir adsorption isotherm.

Keywords
Corrosion inhibitor, Monoethanolamine, Methyl methacrylate, Phosphoric acid.

References
[1] Chandrabhan Verma et al., “An Overview on Plant Extracts as Environmental Sustainable and Green Corrosion Inhibitors for Metals and Alloys in Aggressive Corrosive Media,” Journal of Molecular Liquids, vol. 266, pp. 577-590, 2018.
[CrossRef] [Google Scholar] [Publisher Link]
[2] Saviour A. Umoren et al., “A Critical Review on the Recent Studies on Plant Biomaterials as Corrosion Inhibitors for Industrial Metals,” Journal of Industrial and Engineering Chemistry, vol. 76, pp. 91-115, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[3] Marko Chigondo, and Fidelis Chigondo, “Recent Natural Corrosion Inhibitors for Carbon Steel: An Overview,” Journal of Chemistry, vol. 2016, pp. 1-8, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[4] P. Muthukrishnan, B. Jeyaprabha, and P. Prakash, “Mild Steel Corrosion Inhibition by Aqueous Extract of Hyptis Suaveolens Leaves,” International Journal of Industrial Chemistry, vol. 5, pp. 1-11, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[5] Jasdeep Kaur, Neha Daksh, and Akhil Saxena, “Corrosion Inhibition Applications of Natural and Eco-Friendly Corrosion Inhibitors on Steel in the Acidic Environment: An Overview,” Arabian Journal for Science and Engineering, vol. 47, pp. 57-74, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[6] Amel Kouache et al., “Experimental and Theoretical Studies of Inula Viscosa Extract as a Novel Eco-Friendly Corrosion Inhibitor for Carbon Steel in 1 M HCl,” Journal of Adhesion Science and Technology, vol. 36, no. 9, pp. 988-1016, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[7] Gang Lu et al., “Corrosion Protection of Iron Surface Modified by Poly(Methyl Methacrylate) Using Surface-Initiated Atom Transfer Radical Polymerization (SI-ATRP), Colloid and Polymer Science, vol. 288, pp. 1445-1455, 2010.
[CrossRef] [Google Scholar] [Publisher Link]
[8] M.A. Shaymardanova et al., Study of Process of Obtaining Monopotassium Phosphate Based on Monosodium Phosphate and Potassium Chloride,” Chemistry Problems, no. 3, pp. 279-293, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[9] Fariborz Atabaki, Shahrzad Jahangiri, and Zohreh Pahnavar, “Thermodynamic and Electrochemical Investigations of Poly (Methyl Methacrylate–Maleic Anhydride) as Corrosion Inhibitors for Carbon Steel in 0.5 M HCl,” Protection of Metals and Physical Chemistry of Surfaces, vol. 55, pp. 1161-1172, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[10] Kh. S. Beknazarov et al., “The Inhibition of the Corrosion of Carbon Steel by Oligomeric Corrosion Inhibitors in Different Media,” International Polymer Science and Technology, vol. 42, no. 4, pp. 33-38, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[11] S. Kumar, “Eco-Friendly Corrosion Inhibitors: Synergistic Effect of Ethanol Extracts of Calotropis for Corrosion of Carbon Steel in Acid Media Using Mass Loss and Thermometric Technique at Different Temperature,” Protection of Metals and Physical Chemistry of Surfaces, vol. 52, pp. 376-380, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[12] Estela K.K. Baldin et al., “Ammonium Molybdate Added in Hybrid Films Applied on Tinplate: Effect of the Concentration in the Corrosion Inhibition Action,” Thin Solid Films, vol. 600, pp. 146-156, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[13] M. Mouanga et al., “A Localized Approach to Study the Effect of Cerium Salts as Cathodic Inhibitor on Iron/Aluminum Galvanic Coupling,” Corrosion Science, vol. 90, pp. 491-502, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[14] N. Rezaee, M.M. Attar, and B. Ramezanzadeh, “Studying Corrosion Performance, Microstructure and Adhesion Properties of a Room Temperature Zinc Phosphate Conversion Coating Containing Mn2+ on Mild Steel,” Surface and Coatings Technology, vol. 236, pp. 361- 367, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[15] T.H. Muster et al., “A Combinatorial Matrix of Rare Earth Chloride Mixtures as Corrosion Inhibitors of AA2024-T3: Optimisation Using Potentiodynamic Polarisation and EIS,” Electrochemistry Acta, vol. 67, pp. 95-103, 2012.
[CrossRef] [Google Scholar] [Publisher Link]
[16] Nomozov Abror Karim Ugli et al., “Salsola Oppositifolia Acid Extract as a Green Corrosion Inhibitor for Carbon Steel,” Indian Journal of Chemical Technology, vol. 30, no. 6, pp. 872-877, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[17] I.A. Wonnie Ma et al., “A Concise Review on Corrosion Inhibitors: Types, Mechanisms and Electrochemical Evaluation Studies,” Journal of Coatings Technology and Research, vol. 19, pp. 241-268, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[18] M. Tourabi et al., “3, 5-Diaryl-4-Amino-1, 2, 4-Triazole Derivatives as Effective Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution: Correlation between Anti-Corrosion Activity and Chemical Structure,” Protection of Metals and Physical Chemistry of Surfaces, vol. 53, pp. 548-559, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[19] Ahmed Al-Amiery, Wan Nor Roslam Wan Isahak, and Waleed Khalid Al-Azzawi, “Multi-Method Evaluation of a 2-(1,3,4-Thiadiazole2-yl)Pyrrolidine Corrosion Inhibitor for Carbon sSteel in HCl: Combining Gravimetric, Electrochemical, and DFT Approaches,” Scientific Reports, pp. 1-20, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[20] I. Danaee, and P. Nikparsa, “Electrochemical Frequency Modulation, Electrochemical Noise, and Atomic Force Microscopy Studies on Corrosion Inhibition Behavior of Benzothiazolone for Steel API X100 in 10% HCl Solution,” Journal of Materials Engineering and Performance, vol. 28, pp. 5088-5103, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[21] Ahmed I. Adawy, Mohamed A. Abbas, and Khaled Zakaria, “New Schiff Base Cationic Surfactants as Corrosion Inhibitors for Carbon Steel in Acidic Medium: Weight Loss, Electrochemical and SEM Characterization Techniques,” Research on Chemical Intermediates, vol. 42, pp. 3385-3411, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[22] K.F. Khaled, and Mohammed A. Amin, “Computational and Electrochemical Investigation for Corrosion Inhibition of Nickel in Molar Nitric Acid by Piperidines,” Journal of Applied Electrochemistry, vol. 38, pp. 1609-1621, 2008.
[CrossRef] [Google Scholar] [Publisher Link]
[23] Chenrong Gu, Junying Hu, and Xiankang Zhong, “Evidence of Hydrogen Gas Evolution Accelerating the Cathodic Coating Delamination,” Corrosion Communications, vol. 7, pp. 63-69, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[24] Ambrish Singh et al., “Inhibition of Hydrogen Evolution and Corrosion Protection of Negative Electrode of Lead-Acid Battery by Natural Polysaccharide Composite: Experimental and Surface Analysis,” Journal of Energy Storage, vol. 57, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[25] Mohamed A. Abbas et al., “Synthesis, Characterization, Thermodynamic Analysis and Quantum Chemical Approach of Branched N, N′-Bis(p-Hydroxybenzoyl)-Based Propanediamine and Triethylenetetramine for Carbon Steel Corrosion Inhibition in Hydrochloric Acid Medium,” Arabian Journal for Science and Engineering, vol. 48, pp. 7463-7484, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[26] Abdelkarim Chaouiki et al., “Electrochemical Behavior and Interfacial Bonding Mechanism of New Synthesized Carbocyclic Inhibitor for Exceptional Corrosion Resistance of Steel Alloy: DFTB, MD and Experimental Approaches,” Arabian Journal of Chemistry, vol. 15, no. 12, pp. 1-20, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[27] Anees A. Khadom et al., “Kinetics and Synergistic Effect of Iodide Ion and Naphthylamine for the Inhibition of Corrosion Reaction of Carbon Steel in Hydrochloric Acid,” Reaction Kinetics, Mechanisms and Catalysis, vol. 115, pp. 463-481, 2015.
[CrossRef] [Google Scholar] [Publisher Link]